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About Material Quality  


Stainless Steel - Grade 304

Chemical Formula :
Fe, <0.8% C, 17.5-20% Cr, 8-11% Ni, <2% Mn, <1% Si, <0.045% P, <0.03% S

Grade 304 is the standard "18/8" stainless; it is the most versatile and most widely used stainless steel, available in a wider range of products, forms and finishes than any other. It has excellent forming and welding characteristics. The balanced austenitic structure of Grade 304 enables it to be severely deep drawn without intermediate annealing, which has made this grade dominant in the manufacture of drawn stainless parts such as sinks, hollow-ware and saucepans. For these applications it is common to use special "304DDQ" (Deep Drawing Quality) variants. Grade 304 is readily brake or roll formed into a variety of components for applications in the industrial, architectural, and transportation fields. Grade 304 also has outstanding welding characteristics. Post-weld annealing is not required when welding thin sections. Grade 304L, the low carbon version of 304, does not require post-weld annealing and so is extensively used in heavy gauge components (over about 6mm). Grade 304H with its higher carbon content finds application at elevated temperatures. The austenitic structure also gives these grades excellent toughness, even down to cryogenic temperatures.

Composition
Typical compositional ranges for grade 304 stainless steels are given in table 1.

Table 1. Composition ranges for 304 grade stainless steel

Grade

C

Mn

Si

P

S

Cr

Mo

Ni

N

304

min.

max.

-

0.08

-

2.0

-

0.75

-

0.045

-

0.030

18.0

20.0

-

8.0

10.5

-

0.10

304L

min.

max.

-

0.030

-

2.0

-

0.75

-

0.045

-

0.030

18.0

20.0

-

8.0

12.0

-

0.10

304H

min.

max.

0.04

0.10

-

2.0

-

0.75

-0.045

-

0.030

18.0

20.0

-

8.0

10.5

-

Mechanical Properties
Typical mechanical properties for grade 304 stainless steels are given in table 2.

Table 2. Mechanical properties of 304 grade stainless steel

Grade

Tensile Strength (MPa) min

Yield Strength 0.2% Proof (MPa) min

Elongation (% in 50mm) min

Hardness

Rockwell B (HR B) max

Brinell (HB) max

304

515

205

40

92

201

304L

485

170

40

92

201

304H

515

205

40

92

201

304H also has a requirement for a grain size of ASTM No 7 or coarser.

Physical Properties
Typical physical properties for annealed grade 304 stainless steels are given in table 3.

Table 3. Physical properties of 304 grade stainless steel in the annealed condition

Grade

Density (kg/m3)

Elastic Modulus (GPa)

Mean Coefficient of Thermal Expansion (mm/m/°C)

Thermal Conductivity (W/m.K)

Specific Heat 0-100°C (J/kg.K)

Electrical Resistivity (nW.m)

0-100°C

0-315°C

0-538°C

at 100°C

at 500°C

304/L/H

8000

193

17.2

17.8

18.4

16.2

21.5

500

720

Grade Specification Comparison
Approximate grade comparisons for 304 stainless steels are given in table 4.

Table 4. Grade specifications for 304 grade stainless steel

Grade

UNS No

Old British

Euronorm

Swedish SS

Japanese JIS

BS

En

No

Name

304

S30400

304S31

58E

1.4301

X5CrNi18-10

2332

SUS 304

304L

S30403

304S11

-

1.4306

X2CrNi19-11

2352

SUS 304L

304H

S30409

304S51

-

1.4948

X6CrNi18-11

-

-

These comparisons are approximate only. The list is intended as a comparison of functionally similar materials not as a schedule of contractual equivalents. If exact equivalents are needed original specifications must be consulted.

Possible Alternative Grades
Possible alternative grades to grade 304 stainless steels are given in table 5.

Table 5. Possible alternative grades to 304 grade stainless steel

Grade

Why it might be chosen instead of 304

301L

A higher work hardening rate grade is required for certain roll formed or stretch formed components.

302HQ

Lower work hardening rate is needed for cold forging of screws, bolts and rivets.

303

Higher machinability needed, and the lower corrosion resistance, formability and weldability are acceptable.

316

Higher resistance to pitting and crevice corrosion is required, in chloride environments

321

Better resistance to temperatures of around 600-900°C is needed…321 has higher hot strength.

3CR12

A lower cost is required, and the reduced corrosion resistance and resulting discolouration are acceptable.

430

A lower cost is required, and the reduced corrosion resistance and fabrication characteristics are acceptable.

Corrosion Resistance
Excellent in a wide range of atmospheric environments and many corrosive media. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 60°C. Considered resistant to potable water with up to about 200mg/L chlorides at ambient temperatures, reducing to about 150mg/L at 60°C.

Heat Resistance
Good oxidation resistance in intermittent service to 870°C and in continuous service to 925°C. Continuous use of 304 in the 425-860°C range is not recommended if subsequent aqueous corrosion resistance is important. Grade 304L is more resistant to carbide precipitation and can be heated into the above temperature range.

Grade 304H has higher strength at elevated temperatures so is often used for structural and pressure-containing applications at temperatures above about 500°C and up to about 800°C. 304H will become sensitised in the temperature range of 425-860°C; this is not a problem for high temperature applications, but will result in reduced aqueous corrosion resistance.